When I got my samsung LE32A456 I imediatly went serching for profetionaly calibrated settings for it alas there isnt any posted, but what I got from reading setings posted on various sites on on lots of different tvs is that those in the know generaly have sharpnes set between 0 to 20 (max) out of 100.
In my own experience this works quite well for SD sources and does no harm to HD, and that the edge enhancement feature on my set helped my poor old V box no end (the pictures that bad processing actually benefits it!) but it makes no difference on SKY HD. you could use a movie with a THX calibration feature (like star wars) to set the sharpness and see how that goes
Current rig
Cambridge audio DVD89,Sony TA-F270,Tannoy F1 customs